Situated within a 500-metre distance of Piazza Bovio Piombino Livorno, Hotel Centrale Piombino includes 35 rooms with views of the city. Wi-Fi is accessible in public areas and private parking is provided on site.

Museo del Mare e Acquario is not far from this hotel, and the history museum "Museo del Castello e delle Ceramiche Medievali" is located a 16-minute walk away. The Centrale is within 550 metres of Torre dell'Orologio Castle and 110 km from Galileo Galilei airport. Spiaggialunga is 10 minutes' drive from the 4-star hotel. Piombino Da Vinci bus station is steps away from this property.

The rooms at the hotel provide guests with a flat-screen TV with satellite channels, as well as comforts such as an air conditioner. Bathrooms feature a bidet, a separate toilet, and a shower along with a hairdryer and bath sheets.

Hotel Centrale serves a buffet breakfast every morning. This accommodation features an à la carte restaurant serving Italian cuisine. The hotel invites guests to the lounge bar to relax with a drink. The restaurant Al Baccanale is 250 metres away.